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el_kyleIf they're new they should be very snug but by no means painful. In a new boot and especially the first day out on them in a long while, it's common for some fatigue because your foot isn't used to an environment of being enclosed by a firm piece of plastic.
Out of curiosity where specifically are you experiencing the pain? Sooner rather than later I'd sit down with a bootfitter and get a proper evaluation.
jnorrmanUpdate: got them heat molded and problem is solved